Flow batteries have demonstrated cycle lives of over 10,000 cycles with minimal capacity degradation. These systems typically have wider operating temperature ranges than conventional rechargeable batteries, and they are generally present little or no fire hazard and limited toxicity. But those advantages come with associated costs.
Flow batteries are a developing and immature technology and are, therefore, still declining in cost. Competitive systems based on Lithium-ion batteries, on the other hand, benefit from the commodity pricing associated with the highly-developed status of Lithium-ion technology. The plumbing for flow batteries, the need for controls, cooling systems, pumps, and other active components also contributed to the cost of flow batteries compared with conventional rechargeable batteries such as lithium-ions. Those “balance of system” elements also add maintenance costs for flow batteries.
In addition, flow batteries typically need a finite time for startup that can range from a few tens of milliseconds to tens of seconds, or even longer, to reach full power. Ramp up times can be kept to the millisecond range if the pumps are kept running continuously.
Flow batteries are scalable
Vanadium flow batteries, and flow batteries, in general, offer users the ability to scale the system in terms of both energy storage capacity and power delivery capability. As shown below, flow batteries store electricity as chemical energy in two large tanks. The tanks are filled with salts dissolved in inorganic acids. The tanks are connected with one or more electrochemical cells via which the flow batteries are charged and discharged. The surface area of the cells determines the output of the batteries. Capacity can be changed easily by increasing the size of the tanks.
From microgrids to grid-scale storage with renewables
As the potential size of flow batteries increases, so does the potential to use flow batteries in utility-scale installations. In applications such as renewables integration, load shifting, and peak shaving, flow batteries compete with other technologies such as various rechargeable batteries and thermal energy storage. In wind farms, flow batteries can store excess electricity produced when it is very windy and then feed it back into the grid when the wind dies down.
According to a recent study by the National Renewable Energy Laboratory (NREL), emerging large-scale energy storage technologies are making 100% penetration by renewable energy sources an increasing possibility. NREL’s Renewable Electricity Futures Study estimated that 120 gigawatts of storage would be needed across the continental United States by 2050 when the scenario imagined a future where 80% of electricity will come from renewable resources. The country currently has 22 gigawatts of storage from pumped hydropower, and another gigawatt in batteries.
Other utility-scale and microgrid applications for flow batteries include:
- Behind the meter storage for lower utility rates
- Volt/VAR support
- Peak shaving and replacing high-cost natural gas and diesel generators
- Electricity arbitrage between high-cost and low-cost suppliers and markets
Remote power and telecommunications backup power
For remote power and telecommunications backup power 48-Vdc zinc-bromine flow batteries, such as those offered by Redflow, solve many of the problems that impact telecommunications providers These include the ability to operate in warm (up to 50 degrees C, 122 degrees F) and dusty conditions without active cooling; long-term storage at any state of charge, from empty to full for up to 10 years, without damaging the battery; and construction materials with little resale value, making them less attractive to thieves. These features can make flow batteries especially desirable in developing nations in Africa, Asia, and the Indian subcontinent, where wireless telephony and Internet access have leapfrogged wired telco infrastructure, often in areas with unstable or no grid access.
Redflow also offers a Large Scale Battery (LSB) reference platform that demonstrates a straightforward and proven model for deploying the company’s zinc-bromine flow batteries in large energy storage systems. Deployed in a six-meter (20-foot) shipping container, Redflow’s LSB reference platform contains as many as 45 zinc-bromine flow batteries and six 12kW battery inverter/chargers, providing users with 24/7 monitoring and scalable energy capacity to as much as 450 kilowatt-hours.